I haven't used my siphon cups for their intended purposes yet. I only use them to store my disassembled paint tips while they are soaking in alcohol

If your gravity cup works great but your siphon cup does not, that rules out the possibility that your tip might be loose. Paint thinning ratio is also not a problem because you're only spraying thinner. The only thing I can think about is: did you attach the straw that comes with the cup to the cup lid?