Are you using a 1/1 mix ratio resin? If you are, you should not put more of one part than the other in while mixing. While mixing a 10/1 silicone, it is always a good idea to add a drop or two extra of the catalyst, when dealing with resin, it is a different story. Yes, I have had the problem you describe when I measured improperly. Next mix, try mixing it to spec and see what happens. Most resins you can de-mold in a half hour or so. I can't understand you having to wait so long to pull the pieces from the mold??
Oh yeah, use some rubbing alcohol to clean out your molds before pouring the next batch of resin else you will end up with the same sticky mess on the next pieces.